In 1952, Kenichi Fukui published a paper in the Journal of Chemical Physics titled "A molecular theory of reactivity in aromatic hydrocarbons." He later received the 1981 Nobel Prize in Chemistry for his investigations into the mechanisms of chemical reactions, with his prize-winning work focused on the role of frontier orbitals in chemical reactions, specifically that molecules share loosely bonded electrons which occupy the frontier orbitals, that is the Highest Occupied Molecular Orbital ( HOMO) and the Lowest Unoccupied Molecular Orbital ( LUMO). ![]() On the list of countries by research and development spending, Japan is third on the list, behind the United States and China.Ĭhemistry Frontier Molecular Orbital Theory In the natural sciences, the number of Japanese winners of the Nobel Prize has been second only to the United States in the 21st century, for contributions made in the 20th century.
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![]() If you used more than one web browser, it is possible that they yield different certificate chains. You can export the intermediate certificates from the web browser. Update NetScaler Gateway with the corresponding intermediate certificates, as they appear in the web browser. If there are any mismatches in intermediate certificates, this is a possible cause. ![]() ![]() Note: Compare all the serial numbers in the certificates and not just the Subject Name. Then, compare all the certificates in the browser's certificate chain with the certificate chain at NetScaler Gateway. You may wish to cross-check this by repeating with more than one web browser (such as with Google Chrome and Mozilla Firefox). To confirm this, visit the NetScaler Gateway website using a web browser, and examine the certificate chain in the web browser. Verify the certificate bindings at the NetScaler Gateway to resolve this issue. This does not mean that the CA certificates currently being used is expired but the CA has since released newer versions of that certificate. This issue may be caused by an out-of-date intermediate certificate installed at NetScaler Gateway. If you are experiencing this issue and you are not a System Administrator, contact your organization’s Help Desk for assistance and refer them to this article. Important! 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